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Issue 9, 2019

Cross coupling of alkylsilicates with acyl chlorides via photoredox/nickel dual catalysis: a new synthesis method for ketones

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Abstract

Photoredox/nickel dual catalysis using easily oxidized bis-catecholato hypercoordinated silicon derivatives as radical sources and acyl chlorides as electrophiles allows a new method of formation of dialkyl and alkyl-aryl ketones as well as dibenzyl ketones which are less easily accessed. Flow chemistry can be used.

Graphical abstract: Cross coupling of alkylsilicates with acyl chlorides via photoredox/nickel dual catalysis: a new synthesis method for ketones

Supplementary files

Article information


Submitted
20 Jan 2019
Accepted
26 Feb 2019
First published
27 Feb 2019

Org. Chem. Front., 2019,6, 1378-1382
Article type
Research Article

Cross coupling of alkylsilicates with acyl chlorides via photoredox/nickel dual catalysis: a new synthesis method for ketones

E. Levernier, V. Corcé, L. Rakotoarison, A. Smith, M. Zhang, S. Ognier, M. Tatoulian, C. Ollivier and L. Fensterbank, Org. Chem. Front., 2019, 6, 1378 DOI: 10.1039/C9QO00092E

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