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Issue 20, 2018
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Silver-catalyzed decarboxylative cascade radical cyclization of tert-carboxylic acids and o-(allyloxy)arylaldehydes towards chroman-4-one derivatives

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Abstract

A convenient silver-catalyzed decarboxylative cascade radical cyclization of tertiary carboxylic acids and o-(allyloxy)arylaldehydes was developed to synthesize 3-alkyl-substituted chroman-4-one derivatives. A series of chroman-4-one derivatives were constructed with moderate to good yields. This procedure offers a practical method for the synthesis of 3-alkyl-substituted chroman-4-one derivatives by a one-pot reaction from easily available reagents.

Graphical abstract: Silver-catalyzed decarboxylative cascade radical cyclization of tert-carboxylic acids and o-(allyloxy)arylaldehydes towards chroman-4-one derivatives

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Publication details

The article was received on 16 Aug 2018, accepted on 02 Sep 2018 and first published on 03 Sep 2018


Article type: Research Article
DOI: 10.1039/C8QO00882E
Citation: Org. Chem. Front., 2018,5, 2925-2929
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    Silver-catalyzed decarboxylative cascade radical cyclization of tert-carboxylic acids and o-(allyloxy)arylaldehydes towards chroman-4-one derivatives

    H. Hu, X. Chen, K. Sun, J. Wang, Y. Liu, H. Liu, B. Yu, Y. Sun, L. Qu and Y. Zhao, Org. Chem. Front., 2018, 5, 2925
    DOI: 10.1039/C8QO00882E

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