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Issue 12, 2018
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ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes

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Abstract

A convenient, mild and high stereoselective C-glycosylation reaction has been developed. Glycosyl acetates were coupled with terminal alkynes via ZnBr2-activation at room temperature. Their applications were further demonstrated by the straightforward synthesis of a key intermediate in the formal synthesis of (+)-varitriol.

Graphical abstract: ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes

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Publication details

The article was received on 13 Apr 2018, accepted on 04 May 2018 and first published on 07 May 2018


Article type: Research Article
DOI: 10.1039/C8QO00380G
Org. Chem. Front., 2018,5, 1962-1966

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    ZnBr2-catalyzed direct C-glycosylation of glycosyl acetates with terminal alkynes

    H. He and H. Qin, Org. Chem. Front., 2018, 5, 1962
    DOI: 10.1039/C8QO00380G

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