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Issue 9, 2018
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Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

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Abstract

A silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols including cyclopropanols, cyclobutanols, cyclopentanols, cyclohexanols and cycloheptanols was described. A variety of common functional groups such as fluoride, chloride, bromide, iodide, trifluoromethyl, cyano and ester groups were compatible.

Graphical abstract: Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

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Article information


Submitted
01 Feb 2018
Accepted
05 Mar 2018
First published
06 Mar 2018

Org. Chem. Front., 2018,5, 1462-1465
Article type
Research Article

Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

B. Xu, D. Wang, Y. Hu and Q. Shen, Org. Chem. Front., 2018, 5, 1462
DOI: 10.1039/C8QO00115D

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