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Issue 10, 2017
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Silver-mediated fluorination of alkyl iodides with TMSCF3 as the fluorinating agent

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Abstract

The first example of a silver-mediated fluorination of alkyl iodides with the Ruppert–Prakash reagent (TMSCF3) as a fluorinating agent has been reported. This reaction is compatible with a variety of functional groups and proceeds under mild reaction conditions. Moreover, we demonstrate that the large surface area of CaF2 dramatically increased the reaction yield.

Graphical abstract: Silver-mediated fluorination of alkyl iodides with TMSCF3 as the fluorinating agent

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Supplementary files

Article information


Submitted
08 Jun 2017
Accepted
26 Jun 2017
First published
27 Jun 2017

Org. Chem. Front., 2017,4, 1958-1961
Article type
Research Article

Silver-mediated fluorination of alkyl iodides with TMSCF3 as the fluorinating agent

L. Wang, X. Jiang and P. Tang, Org. Chem. Front., 2017, 4, 1958
DOI: 10.1039/C7QO00450H

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