Issue 8, 2017
From the journal:

Organic Chemistry Frontiers

Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates†

Yuhan Zhou, ORCID logo *a   Huan Wang, ORCID logo a   Yang Liu, ORCID logo a   Yilong Zhao, ORCID logo a   Chunxia Zhang ORCID logo a  and  Jingping Qu ORCID logo a  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian 116024, P.R. China
E-mail: zhouyh@dl.cn

Abstract

An efficient approach to allylic boronates via iron-catalyzed boration of allylic esters is described. The reactions of allylic esters and bis(pinacolato)diboron (B2pin2) proceed smoothly catalyzed by FeCl2/PPh3. Thus, a wide range of allylic boronates with broad functional-group compatibility are obtained.

Graphical abstract: Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7QO00228A
Article type
Research Article
Submitted
23 Mar 2017
Accepted
09 May 2017
First published
10 May 2017

Org. Chem. Front., 2017,4, 1580-1585

Permissions

Request permissions

Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates

Y. Zhou, H. Wang, Y. Liu, Y. Zhao, C. Zhang and J. Qu, Org. Chem. Front., 2017, 4, 1580 DOI: 10.1039/C7QO00228A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements