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Issue 5, 2017
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5-Azadibenzo[a,g]corannulene

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Abstract

5-Azadibenzo[a,g]corannulene, the first azacorannulene with a nitrogen on the rim, has been synthesized in seven steps from 4-bromoisoquinoline. The strained pyridine ring opens thermally to a polycyclic aromatic nitrile and hydrolytically to an amino aldehyde with the same polycyclic aromatic hydrocarbon framework.

Graphical abstract: 5-Azadibenzo[a,g]corannulene

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Supplementary files

Article information


Submitted
19 Dec 2016
Accepted
09 Jan 2017
First published
19 Jan 2017

Org. Chem. Front., 2017,4, 688-698
Article type
Research Article

5-Azadibenzo[a,g]corannulene

V. M. Tsefrikas, A. K. Greene and L. T. Scott, Org. Chem. Front., 2017, 4, 688
DOI: 10.1039/C6QO00831C

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