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Issue 5, 2016
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Oxidative trifluoromethylthiolation and thiocyanation of amines: a general approach to N–S bond formation

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Abstract

Herein, we described a practical and efficient one-pot oxidative trifluoromethylthiolation of amines. A panel of primary and secondary amines was functionalized in good yields at room temperature. This general approach was further applied to the thiocyanation of anilines and the corresponding products can be readily used as SCN electrophilic sources.

Graphical abstract: Oxidative trifluoromethylthiolation and thiocyanation of amines: a general approach to N–S bond formation

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The article was received on 09 Feb 2016, accepted on 08 Mar 2016 and first published on 16 Mar 2016


Article type: Research Article
DOI: 10.1039/C6QO00064A
Org. Chem. Front., 2016,3, 620-624

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    Oxidative trifluoromethylthiolation and thiocyanation of amines: a general approach to N–S bond formation

    H. Xiong, X. Pannecoucke and T. Besset, Org. Chem. Front., 2016, 3, 620
    DOI: 10.1039/C6QO00064A

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