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Issue 4, 2016

Gold(i) catalyzed [1,3] O → C rearrangement of benzylvinyl ethers

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Abstract

A simple procedure for the preparation of 3-(hetero)arylpropionaldehydes has been developed employing a gold-catalyzed [1,3]-rearrangement of vinyl ethers. Using this protocol, Canthoxal, an aromatic aldehyde used in perfumery, has been prepared on a gram scale.

Graphical abstract: Gold(i) catalyzed [1,3] O → C rearrangement of benzylvinyl ethers

Supplementary files

Article information


Submitted
24 Nov 2015
Accepted
26 Jan 2016
First published
26 Jan 2016

Org. Chem. Front., 2016,3, 453-456
Article type
Research Article
Author version available

Gold(I) catalyzed [1,3] O → C rearrangement of benzylvinyl ethers

C. N. Kona, M. N. Patil and C. V. Ramana, Org. Chem. Front., 2016, 3, 453 DOI: 10.1039/C5QO00397K

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