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Issue 12, 2015
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2′-Cyanoethyl thioglycosides: effective nucleophiles for synthesis of (hetero)aryl thioglycosides under the catalysis of Cu

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Abstract

2′-Cyanoethyl thioglycosides are designed and synthesized, which are demonstrated to function as powerful nucleophiles to a wide variety of organic iodides. The coupling reactions smoothly proceed under the catalysis of Cu to afford the corresponding (hetero)aryl thioglycosides in good to excellent yields.

Graphical abstract: 2′-Cyanoethyl thioglycosides: effective nucleophiles for synthesis of (hetero)aryl thioglycosides under the catalysis of Cu

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Article information


Submitted
07 Sep 2015
Accepted
13 Oct 2015
First published
14 Oct 2015

Org. Chem. Front., 2015,2, 1604-1607
Article type
Research Article

2′-Cyanoethyl thioglycosides: effective nucleophiles for synthesis of (hetero)aryl thioglycosides under the catalysis of Cu

X. Yuan, Y. Kou, L. Yu, Z. Zhang and W. Xue, Org. Chem. Front., 2015, 2, 1604
DOI: 10.1039/C5QO00276A

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