Issue 3, 2014
From the journal:

Organic Chemistry Frontiers

Highly efficient and practical resolution of 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione and stereoselective synthesis of its chiral diamine derivatives†

Bin Wanga  and  Zhenhua Gu*a  

* Corresponding authors

a Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, P. R. China
E-mail: zhgu@ustc.edu.cn

Abstract

Highly efficient and practical resolution of 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione by inclusion complexation with commercially available enantiopure 1,1′-bi-2-naphthol is reported. The structure of the 1 : 1 inclusion complex of the diketone and BINOL was confirmed by single crystal X-ray crystallography.

Graphical abstract: Highly efficient and practical resolution of 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione and stereoselective synthesis of its chiral diamine derivatives

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Article information

DOI
https://doi.org/10.1039/C4QO00011K
Article type
Research Article
Submitted
14 Jan 2014
Accepted
10 Feb 2014
First published
26 Feb 2014

Org. Chem. Front., 2014,1, 271-274

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Highly efficient and practical resolution of 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione and stereoselective synthesis of its chiral diamine derivatives

B. Wang and Z. Gu, Org. Chem. Front., 2014, 1, 271 DOI: 10.1039/C4QO00011K

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