Issue 1, 2014
From the journal:

Organic Chemistry Frontiers

Copper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate with iodo/bromo-aryl triazenes†

Zhang Feng,a   Yu-Lan Xiaoa  and  Xingang Zhang*a  

* Corresponding authors

a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: xgzhang@mail.sioc.ac.cn
Fax: (+86)-21-6416-6128
Tel: (+86)-21-5492-5333

Abstract

A versatile method for the preparation of aryldifluoromethylphosphonates has been developed. This represents the first example of copper-catalyzed difluoroalkylation of ArBr and provides a useful and facile access to diverse aryldifluoromethylphosphonates that are difficult to prepare otherwise.

Graphical abstract: Copper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate with iodo/bromo-aryl triazenes

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Article information

DOI
https://doi.org/10.1039/C3QO00044C
Article type
Research Article
Submitted
18 Nov 2013
Accepted
07 Dec 2013
First published
23 Dec 2013

Org. Chem. Front., 2014,1, 113-116

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Copper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate with iodo/bromo-aryl triazenes

Z. Feng, Y. Xiao and X. Zhang, Org. Chem. Front., 2014, 1, 113 DOI: 10.1039/C3QO00044C

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