Carve designs of MoS2 nanostructures by controlling 3D MoS2 nanomasks

Abstract

The properties of nanomaterials are significantly altered by their topological structures. A new carved MoS₂ nanostructure has been produced by controlling an in situ grown three-dimensional MoS₂ nanomask which was reported recently. The carved molybdenum oxides inside MoS₂ nanomasks have been further reacted with sulfur by encapsulation through the open caps of MoS₂ nanotubes to become MoS₂ nanoflowers with each nanosheet consisting of 6–25 layers (mainly 6–12 layers). Extremely high electrochemical performances have been achieved from the carved MoS₂ nanostructures. A specific capacity of 1569 mA h g⁻¹ at a current rate of 100 mA g⁻¹ after the 176^th cycle has been obtained from the carved MoS₂ nanostructures. The specific capacities tend to be stable even after 200 cycles. The specific capacities of the carved MoS₂ nanostructures are more than twice those of commercially available MoS₂ powders and the reported well designed MoS₂ nanostructures, and even better than the reported MoS₂ composites with conductive carbon nanostructures.