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Issue 7, 2016
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Ionothermal synthesis and magnetic study of a new manganese(II) phosphite with an unprecedented Mn/P ratio

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Abstract

A new layered manganese(II) phosphite, |NH4|4[Mn4(PO3H)6] (JIS-10), has been synthesised via the ionothermal method by using 1-pentyl-3-methylimidazolium bromide ([Pmim]Br) as the solvent. JIS-10 is the first manganese phosphite with a Mn/P ratio of 2/3, whose layered framework is built by the alternate connection of Mn2O9 dimers and PO3H pseudo-tetrahedra. JIS-10 represents an antiferromagnetic dimer system with S = 5/2 for each Mn2+ ion.

Graphical abstract: Ionothermal synthesis and magnetic study of a new manganese(ii) phosphite with an unprecedented Mn/P ratio

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Publication details

The article was received on 18 Jan 2016, accepted on 07 Apr 2016 and first published on 12 Apr 2016


Article type: Research Article
DOI: 10.1039/C6QI00014B
Inorg. Chem. Front., 2016,3, 924-927

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    Ionothermal synthesis and magnetic study of a new manganese(II) phosphite with an unprecedented Mn/P ratio

    T. Su, H. Xing, Y. Li, J. Wu, X. Song, T. Nakano and J. Yu, Inorg. Chem. Front., 2016, 3, 924
    DOI: 10.1039/C6QI00014B

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