Issue 47, 2020
From the journal:

Polymer Chemistry

Step-growth polymerisation of alkyl acrylates via concomitant oxa-Michael and transesterification reactions†

Karin Ratzenböck,ac   David Pahovnik ORCID logo b  and  Christian Slugovc ORCID logo *ac  

* Corresponding authors

a Christian Doppler Laboratory for Organocatalysis in Polymerization, Stremayrgasse 9, A 8010 Graz, Austria

b National Institute of Chemistry, Department of Polymer Chemistry and Technology, Hajdrihova 19, 1000 Ljubljana, Slovenia

c Institute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, A 8010 Graz, Austria
E-mail: slugovc@tugraz.at

Abstract

Herein we propose an auto-tandem catalytic approach towards the preparation of poly(ester–ether)s from simple alkyl acrylates and diols. By combining oxa-Michael addition with transesterification the preparation of hydroxy functionalised acrylate monomers can be avoided.

Graphical abstract: Step-growth polymerisation of alkyl acrylates via concomitant oxa-Michael and transesterification reactions

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Article information

DOI
https://doi.org/10.1039/D0PY01271H
Article type
Communication
Submitted
05 Sep 2020
Accepted
21 Nov 2020
First published
23 Nov 2020
This article is Open Access
Creative Commons BY-NC license

Polym. Chem., 2020,11, 7476-7480

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Step-growth polymerisation of alkyl acrylates via concomitant oxa-Michael and transesterification reactions

K. Ratzenböck, D. Pahovnik and C. Slugovc, Polym. Chem., 2020, 11, 7476 DOI: 10.1039/D0PY01271H

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