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Issue 47, 2018
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Atom-economical, room-temperature, and high-efficiency synthesis of polyamides via a three-component polymerization involving benzoxazines, odorless isocyanides, and water

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Abstract

A novel octylphosphonic acid (OPA)-catalyzed, high-efficiency, three-component polymerization system involving benzoxazines, odorless isocyanides, and water was developed to synthesize polyamide derivatives with satisfactory molecular weights. This polymerization system showed the advantages of atom-economy, wide substrate scope, short reaction time (6 h), atmosphere-insensitivity, and mild reaction conditions (metal-free catalyst and room temperature).

Graphical abstract: Atom-economical, room-temperature, and high-efficiency synthesis of polyamides via a three-component polymerization involving benzoxazines, odorless isocyanides, and water

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Article information


Submitted
27 Aug 2018
Accepted
01 Nov 2018
First published
01 Nov 2018

Polym. Chem., 2018,9, 5566-5571
Article type
Communication

Atom-economical, room-temperature, and high-efficiency synthesis of polyamides via a three-component polymerization involving benzoxazines, odorless isocyanides, and water

J. Zhang, W. Shi, Q. Liu, T. Chen, X. Zhou, C. Yang, K. Zhang and Z. Xie, Polym. Chem., 2018, 9, 5566
DOI: 10.1039/C8PY01256C

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