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Issue 40, 2018
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Enzymatically degradable star polypeptides with tunable UCST transitions in solution and within layer-by-layer films

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Abstract

We report enzymatically degradable, star polypeptides with uniquely sharp and reversible upper critical solution temperature (UCST) behavior in aqueous solutions. UCST transitions of star-poly(L-ornithine-co-L-citrulline) were tunable via degree of uredio modification and/or length of polypeptide arms. Moreover, star polypeptides were assembled into layer-by-layer films with tannic acid and resulting films displayed robust and tunable UCST-triggered swelling transitions.

Graphical abstract: Enzymatically degradable star polypeptides with tunable UCST transitions in solution and within layer-by-layer films

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Publication details

The article was received on 23 Jun 2018, accepted on 18 Sep 2018 and first published on 18 Sep 2018


Article type: Communication
DOI: 10.1039/C8PY00939B
Citation: Polym. Chem., 2018,9, 4979-4983

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    Enzymatically degradable star polypeptides with tunable UCST transitions in solution and within layer-by-layer films

    Q. Zhou, A. Palanisamy, V. Albright and S. A. Sukhishvili, Polym. Chem., 2018, 9, 4979
    DOI: 10.1039/C8PY00939B

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