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Issue 6, 2016
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Star-epoxy mesogen with 1,3,5-triazine core: a model of A4B3 fractal polymerization in a liquid crystalline thermoset media

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Abstract

A star-epoxy monomer (TriaEP) has been synthesized by the creation of a 1,3,5-triazine core. Its association with an aromatic di-amine reveals an A4B3 cross-linked polymer that exhibits a complex mechanism of self-assembly. These architectural aspects, resulting from both fractal polymerization and mesophase growth, are discussed in regard to its outstanding thermo-mechanical properties.

Graphical abstract: Star-epoxy mesogen with 1,3,5-triazine core: a model of A4B3 fractal polymerization in a liquid crystalline thermoset media

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Article information


Submitted
26 Nov 2015
Accepted
12 Dec 2015
First published
16 Dec 2015

Polym. Chem., 2016,7, 1221-1225
Article type
Communication
Author version available

Star-epoxy mesogen with 1,3,5-triazine core: a model of A4B3 fractal polymerization in a liquid crystalline thermoset media

J. Pin, N. Sbirrazzuoli, L. Sacarescu and A. Mija, Polym. Chem., 2016, 7, 1221
DOI: 10.1039/C5PY01884F

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