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Issue 31, 2015
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Synthesis of 1,5-regioregular polytriazoles by efficient NMe4OH-mediated azide–alkyne click polymerization

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Abstract

Aromatic alkynes and azides were successfully polymerized under metal-free conditions using tetramethylammonium hydroxide (NMe4OH) as an organocatalyst at room temperature and soluble 1,5-regioregular polytriazoles P3a–P3e with high molecular weights (Mw up to 56 000) were readily produced in high yields (up to 96%).

Graphical abstract: Synthesis of 1,5-regioregular polytriazoles by efficient NMe4OH-mediated azide–alkyne click polymerization

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Article information


Submitted
05 Feb 2015
Accepted
01 Mar 2015
First published
03 Mar 2015

Polym. Chem., 2015,6, 5545-5549
Article type
Communication

Synthesis of 1,5-regioregular polytriazoles by efficient NMe4OH-mediated azide–alkyne click polymerization

Y. Liu, J. Wang, D. Huang, J. Zhang, S. Guo, R. Hu, Z. Zhao, A. Qin and B. Z. Tang, Polym. Chem., 2015, 6, 5545
DOI: 10.1039/C5PY00186B

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