Jump to main content
Jump to site search

Issue 4, 2013
Previous Article Next Article

Anchimeric assistance on sequence regulation in partial modification of isotactic poly(propargyl methacrylate) by click reaction

Author affiliations

Abstract

Cu-catalyzed click reaction of highly isotactic poly(propargyl methacrylate) with organic azides with a weakly coordinating monoamine was found to proceed to form blocky segments from 1H NMR observation of monomer-sequence sensitive peak-splittings in the partially modified polymer, while the reaction with a highly coordinative triamine proceeded in a random fashion along the polymer chain.

Graphical abstract: Anchimeric assistance on sequence regulation in partial modification of isotactic poly(propargyl methacrylate) by click reaction

Back to tab navigation

Article information


Submitted
18 Nov 2012
Accepted
08 Dec 2012
First published
10 Dec 2012

Polym. Chem., 2013,4, 887-890
Article type
Communication

Anchimeric assistance on sequence regulation in partial modification of isotactic poly(propargyl methacrylate) by click reaction

T. Kitaura, H. Tomioka, N. Fukatani and T. Kitayama, Polym. Chem., 2013, 4, 887
DOI: 10.1039/C2PY20996A

Social activity

Search articles by author

Spotlight

Advertisements