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Issue 6, 2010
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Catalyticpolymerization of ε-caprolactone in air

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Abstract

A highly efficient, catalytic open-air ring opening polymerization for cyclic esters is reported. Using titanium alkoxides, Ti(OiPr)4 and Ti(OnBu)4, as catalysts reproducible ROPs even with high monomer/initiator ratios without protecting gas are feasible.

Graphical abstract: Catalytic polymerization of ε-caprolactone in air

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Article information


Submitted
05 Apr 2010
Accepted
07 Apr 2010
First published
27 May 2010

Polym. Chem., 2010,1, 834-836
Article type
Communication

Catalytic polymerization of ε-caprolactone in air

A. Pärssinen, M. Kohlmayr, M. Leskelä, M. Lahcini and T. Repo, Polym. Chem., 2010, 1, 834
DOI: 10.1039/C0PY00107D

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