Jump to main content
Jump to site search

Issue 6, 2010
Previous Article Next Article

Dispersion nitroxide mediated polymerization of methyl methacrylate in supercritical carbon dioxide using in situ formed stabilizers

Author affiliations

Abstract

Controlled dispersion nitroxide mediated polymerization (NMP) of methyl methacrylate (MMA) was successfully carried out in supercritical carbon dioxide (scCO2) in the presence of a CO2-philic perfluorinated stabilizer generated “in situ”. This is an efficient green approach for preparing free flowing PMMA powder consisting of small sized microspheres.

Graphical abstract: Dispersion nitroxide mediated polymerization of methyl methacrylate in supercritical carbon dioxide using in situ formed stabilizers

Back to tab navigation

Supplementary files

Article information


Submitted
26 Feb 2010
Accepted
29 Mar 2010
First published
13 Apr 2010

Polym. Chem., 2010,1, 837-840
Article type
Communication

Dispersion nitroxide mediated polymerization of methyl methacrylate in supercritical carbon dioxide using in situ formed stabilizers

B. Grignard, T. Phan, D. Bertin, D. Gigmes, C. Jérôme and C. Detrembleur, Polym. Chem., 2010, 1, 837 DOI: 10.1039/C0PY00066C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.


Social activity

Search articles by author

Spotlight

Advertisements