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Issue 2, 2018

Visible-light-driven two-way photoisomerization of 1-(1-pyrenyl)-2-(2-quinolyl)ethylene in neutral and protonated forms

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Abstract

Diarylethylenes with large π-systems often lose their photochemical activity (the size effect). 1-(1-Pyrenyl)-2-(2-quinolyl)ethylene (1P2QE), despite having a large conjugated π-system of 28 electrons, undergoes two-way reversible transcis photoisomerization both in the neutral and protonated forms with quantum yields as high as 0.13–0.83. For the neutral 1P2QE, experimental data and quantum-chemical calculations indicate a diabatic (nonadiabatic) reaction mechanism. Due to high photoisomerization quantum yields and the long-wavelength absorption band at 340–460 nm and 390–560 nm for the neutral and protonated compounds, respectively, 1P2QE can be used as a molecular photoswitch that is sensitive to visible light.

Graphical abstract: Visible-light-driven two-way photoisomerization of 1-(1-pyrenyl)-2-(2-quinolyl)ethylene in neutral and protonated forms

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Article information


Submitted
26 Sep 2017
Accepted
08 Dec 2017
First published
08 Dec 2017

This article is Open Access

Photochem. Photobiol. Sci., 2018,17, 213-220
Article type
Paper

Visible-light-driven two-way photoisomerization of 1-(1-pyrenyl)-2-(2-quinolyl)ethylene in neutral and protonated forms

M. F. Budyka and V. M. Li, Photochem. Photobiol. Sci., 2018, 17, 213 DOI: 10.1039/C7PP00359E

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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