Issue 3, 2012
From the journal:

Photochemical & Photobiological Sciences

N-Acyl-N-carboxymethyl-2-nitroaniline and its analogues: a new class of water-soluble photolabile precursor of carboxylic acids†‡

Takuya Honda,a   Atsuya Momotakea  and  Tatsuo Arai*a  

* Corresponding authors

a Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki, Japan
E-mail: arai@chem.tsukuba.ac.jp
Fax: +81-298-53-6503
Tel: +81-298-53-4315

Abstract

The synthesis and photochemistry of a new class of water-soluble, photolabile protecting group, the N-carboxymethyl-2-nitroanilinyl (CNA) group, are described. All three CNA-caging compounds synthesized underwent clean photochemical reaction in aqueous buffer solution to produce the intended product of acetic acid, along with the corresponding nitroso aromatic.

Graphical abstract: N-Acyl-N-carboxymethyl-2-nitroaniline and its analogues: a new class of water-soluble photolabile precursor of carboxylic acids

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Article information

DOI
https://doi.org/10.1039/C2PP05322E
Article type
Communication
Submitted
30 Sep 2011
Accepted
04 Dec 2011
First published
20 Dec 2011

Photochem. Photobiol. Sci., 2012,11, 493-496

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N-Acyl-N-carboxymethyl-2-nitroaniline and its analogues: a new class of water-soluble photolabile precursor of carboxylic acids

T. Honda, A. Momotake and T. Arai, Photochem. Photobiol. Sci., 2012, 11, 493 DOI: 10.1039/C2PP05322E

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