Issue 7, 2009
From the journal:

Photochemical & Photobiological Sciences

Physical and chemical quenching rates and their influence on stereoselective photooxygenation of oxazolidinone-functionalized enecarbamates†‡

Marissa R. Solomon,a   J. Sivaguru,*b   Steffen Jockusch,a   Waldemar Adam*cd  and  Nicholas J. Turro*ae  

* Corresponding authors

a The Department of Chemistry, Columbia University, New York, NY, USA

b Department of Chemistry and Molecular Biology, North Dakota State University, Fargo, ND, USA
E-mail: sivaguru.jayaraman@ndsu.edu

c Institut für Organische Chemie, Universität Würzburg, Würzburg, Germany
E-mail: wadam@chemie.uni-wuerzburg.de

d The Department of Chemistry, University of Puerto Rico, Facundo Bueso 110, Rio Piedras, PR, USA

e The Department of Chemical Engineering, Columbia University, New York, NY, USA
E-mail: njt3@columbia.edu

Abstract

Physical and chemical quenching rate constants were measured for the reaction of singlet oxygen with oxazolidinone-functionalized enecarbamates to investigate the role of vibrational deactivation in product stereoselectivity.

Graphical abstract: Physical and chemical quenching rates and their influence on stereoselective photooxygenation of oxazolidinone-functionalized enecarbamates

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Article information

DOI
https://doi.org/10.1039/B903848E
Article type
Communication
Submitted
24 Feb 2009
Accepted
12 Mar 2009
First published
24 Mar 2009

Photochem. Photobiol. Sci., 2009,8, 912-915

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Physical and chemical quenching rates and their influence on stereoselective photooxygenation of oxazolidinone-functionalized enecarbamates

M. R. Solomon, J. Sivaguru, S. Jockusch, W. Adam and N. J. Turro, Photochem. Photobiol. Sci., 2009, 8, 912 DOI: 10.1039/B903848E

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