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Issue 7, 2002
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Inclusion compounds of binaphthol with xylidines: structures, selectivity and kinetics of desolvation

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Abstract

The inclusion compounds of binaphthol with three isomers of xylidine have been studied in terms of their structures and infra-red spectra. Competition experiments show that the selectivity of enclathration follows the trend: 2,6-xylidine > 2,3-xylidine3,5-xylidine. The kinetics of desolvation have been analysed and the activation energies established.

Graphical abstract: Inclusion compounds of binaphthol with xylidines: structures, selectivity and kinetics of desolvation

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Article information


Submitted
06 Dec 2001
Accepted
30 Apr 2002
First published
31 May 2002

J. Chem. Soc., Perkin Trans. 2, 2002, 1246-1250
Article type
Paper

Inclusion compounds of binaphthol with xylidines: structures, selectivity and kinetics of desolvation

L. R. Nassimbeni and H. Su, J. Chem. Soc., Perkin Trans. 2, 2002, 1246
DOI: 10.1039/B204190C

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