Nondegenerate equilibrium in (2-propyl)cycloalkyl cations. Comparison of (2-propyl)cyclopentyl and (2-propyl)cyclohexyl cation using 13C NMR spectroscopy, equilibrium isotope effects and quantum chemical calculations†
Abstract
Tertiary (2-propyl)cyclopentyl and (2-propyl)cyclohexyl carbocations were investigated by