Issue 7, 2001

Solvent effects on the NMR shieldings of nitrogen atoms in azole and azine systems: their counterparts in the gas phase

Abstract

The 14N shieldings of 14 pyrrole and 39 pyridine nitrogens belonging to azoles, oxazoles, thiazoles, azines and indolizines measured in 13 different solvents in the same laboratory by Witanowski et al. are examined in the light of the solvent polarity/polarizability (SPP), solvent acidity (SA) and solvent basicity (SB) pure solvent scales. The results are explained in terms of the structural properties of the compounds. Based on the analysis of the solvent effect, the corresponding 14N shieldings in the gas phase for the 53 nitrogens studied are obtained, the experimental determination of which is a major challenge.

Graphical abstract: Solvent effects on the NMR shieldings of nitrogen atoms in azole and azine systems: their counterparts in the gas phase

Article information

Article type
Paper
Submitted
31 Jan 2001
Accepted
26 Apr 2001
First published
25 May 2001

J. Chem. Soc., Perkin Trans. 2, 2001, 1117-1123

Solvent effects on the NMR shieldings of nitrogen atoms in azole and azine systems: their counterparts in the gas phase

J. Catalán, J. Chem. Soc., Perkin Trans. 2, 2001, 1117 DOI: 10.1039/B101084K

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