Issue 2, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Interplay between cone and partial-cone geometry in doubly-bridged calix[8]arenes investigated by X-ray and 2D NMR

Corrada Geraci,a   Alessandra Bottino,a   Mario Piattelli,a   Enrico Gavuzzob  and  Placido Neri*c  

* Corresponding authors

a Istituto per lo Studio delle Sostanze Naturali di Interesse Alimentare, Chimico-Farmaceutico, C.N.R., Via del Santuario 110, Valverde (CT), Italy

b Istituto di Strutturistica Chimica “G. Giacomello”, C.N.R., Area della Ricerca di Roma, Montelibretti (RM), Italy

c Dipartimento di Chimica, Università di Salerno, Via S. Allende, Baronissi (SA), Italy

Abstract

X-Ray crystallography proves the occurrence in 1,5∶3,7-doubly-bridged calix[8]arenes of a 34-cone geometry which can be transformed, in analogy to calix[4]arenes, to an unprecedented 34-partial-cone arrangement by proper alkylation of the free OH groups.

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Article information

DOI
https://doi.org/10.1039/A909410E
Article type
Communication
Submitted
29 Nov 1999
Accepted
03 Dec 1999
First published
26 Jan 2000

J. Chem. Soc., Perkin Trans. 2, 2000, 185-187

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Interplay between cone and partial-cone geometry in doubly-bridged calix[8]arenes investigated by X-ray and 2D NMR

C. Geraci, A. Bottino, M. Piattelli, E. Gavuzzo and P. Neri, J. Chem. Soc., Perkin Trans. 2, 2000, 185 DOI: 10.1039/A909410E

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