Issue 3, 1985

A structure–reactivity relationship for the basicity of aza-arenes

Abstract

A semi-empirical reactivity index for the simple prediction of nitrogen basicities (pKa values) of aza-arenes is presented, based on the concept of an effective potential W for the valence electrons on aza-nitrogen. Analysis of results for aza-benzenes and -naphthalenes indicates that the basicities are highly sensitive to intramolecular long range effects.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1985, 417-419

A structure–reactivity relationship for the basicity of aza-arenes

J. Spanget-Larsen, J. Chem. Soc., Perkin Trans. 2, 1985, 417 DOI: 10.1039/P29850000417

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