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Issue 8, 1983
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Hydride transfer from cyclohexadienyl anions: the reaction between the hydride Meisenheimer adduct of 2,4-dinitroaniline and 1,3,5-trinitrobenzene

Abstract

The hydride Meisenheimer adduct of 2,4-dinitroaniline transfers hydride to 1,3,5-trinitrobenzene to form its corresponding hydride Meisenheimer adduct. The reaction is practically irreversible. In dilute solution in dimethyl sulphoxide it exhibits second-order kinetics and the observation of several sharp isosbestic points shows that it occurs without formation of any detectable intermediate species.

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Article information


J. Chem. Soc., Perkin Trans. 2, 1983, 1197-1198
Article type
Paper

Hydride transfer from cyclohexadienyl anions: the reaction between the hydride Meisenheimer adduct of 2,4-dinitroaniline and 1,3,5-trinitrobenzene

P. J. Atkins, V. Gold and W. N. Wassef, J. Chem. Soc., Perkin Trans. 2, 1983, 1197
DOI: 10.1039/P29830001197

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