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Transient triplet carbenes have been converted into relatively long-lived iminoxyls by reaction with nitric oxide and hence been detected indirectly by e.s.r. spectroscopy. The process is formally analogous to spin trapping of monoradicals by nitrones and nitroso-compounds. Triplet nitrenes could not be trapped in this way.
A. R. Forrester and J. S. Sadd, J. Chem. Soc., Perkin Trans. 2, 1982, 1273 DOI: 10.1039/P29820001273
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