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Issue 14, 1976
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Relative reactivities of ion-pairs of the 1,3-diphenylallyl carbanion towards fluorene

Abstract

The kinetics of the protonation of ion-pairs of the 1,3-diphenylallyl carbanion by fluorene have been studied spectrophotometrically. Where lithium is the counterion, the loose ion-pair reacts about one hundred times faster than the tight ion-pair. The tight ion-pairs of the sodium salts react four or five orders of magnitude faster than the lithium tight ion-pairs.

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Article information


J. Chem. Soc., Perkin Trans. 2, 1976, 1636-1641
Article type
Paper

Relative reactivities of ion-pairs of the 1,3-diphenylallyl carbanion towards fluorene

G. C. Greenacre and R. N. Young, J. Chem. Soc., Perkin Trans. 2, 1976, 1636
DOI: 10.1039/P29760001636

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