Issue 12, 1976

Reactions over metal catalysts. Part II. Hydrogenolysis of 3,3-dimethylnortricyclene and nortricyclene-3-spirocyclopropane

Abstract

Hydrogenolysis of 3,3-dimethylnortricyclene in solution or in the vapour phase over a series of palladium and platinum catalysts gives a mixture of 2,2- and 7,7-dimethylnorbornanes with the latter predominating. Hydrogenolysis over palladium on pumice catalyst gives a mixture of products including several which arise from carbon–carbon bond breaking and formation. The formation of this latter type of product is more prevalent in reactions of nortricyclene-3-spirocyclopropane (5).

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1976, 1412-1414

Reactions over metal catalysts. Part II. Hydrogenolysis of 3,3-dimethylnortricyclene and nortricyclene-3-spirocyclopropane

M. N. Akhtar, J. J. Rooney and W. R. Jackson, J. Chem. Soc., Perkin Trans. 2, 1976, 1412 DOI: 10.1039/P29760001412

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