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Issue 1, 1999
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Enantiocontrolled synthesis of naturally occurring octadecadienoic acid derivatives, self-defensive substances against rice blast disease, by means of the Sharpless asymmetric epoxidation of unsymmetrical divinylmethanol 1

Abstract

(11S,12S,13S )-(9Z,15Z )- and (11R,12S,13S )-(9Z,15Z )-11-hydroxy-12,13-epoxyoctadecadienoic acids and (11R,12S,13S )-(9Z,15Z )-11,12,13-trihydroxyoctadecadienoic acid, self-defensive substances against the rice blast disease, were synthesised enantioselectively by employing the Sharpless asymmetric epoxidation reaction of the unsymmetrical divinylmethanol, as a key step.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1999, 23-30
Article type
Paper

Enantiocontrolled synthesis of naturally occurring octadecadienoic acid derivatives, self-defensive substances against rice blast disease, by means of the Sharpless asymmetric epoxidation of unsymmetrical divinylmethanol 1

T. Honda, M. Ohta and H. Mizutani, J. Chem. Soc., Perkin Trans. 1, 1999, 23
DOI: 10.1039/A808114J

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