Jump to main content
Jump to site search

Issue 23, 1998
Previous Article Next Article

Direct hydroperoxygenation of conjugated olefins catalyzed by cobalt(II) porphyrin

Abstract

A novel and direct synthesis of hydroperoxy compounds from various types of conjugated olefins was established via cobalt(II) porphyrin-catalyzed hydroperoxygenation. The reaction of α,β,γ,δ-unsaturated carbonyl compounds, acrylic esters, α-substituted acrylic esters and styrene derivatives with molecular oxygen and triethylsilane in the presence of a catalytic amount of cobalt(II) porphyrin proceeded rapidly to give the corresponding hydroperoxygenated compounds in high or moderate yields.

Back to tab navigation

Article information


J. Chem. Soc., Perkin Trans. 1, 1998, 3989-3998
Article type
Paper

Direct hydroperoxygenation of conjugated olefins catalyzed by cobalt(II) porphyrin

K. Sugamoto, Y. Matsushita and T. Matsui, J. Chem. Soc., Perkin Trans. 1, 1998, 3989
DOI: 10.1039/A805888A

Search articles by author

Spotlight

Advertisements