Issue 15, 1996
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Comparison of microbiologically and enzymatically mediated Baeyer–Villiger oxidations: synthesis of optically active caprolactones

Véronique Alphand,   Roland Furstoss,   Sandrine Pedragosa-Moreau,   Stanley M. Roberts  and  Andrew J. Willetts  

Abstract

Optically active α-substituted caprolactones (7-substituted oxepan-2-ones) were obtained by biocatalysed Baeyer–Villiger oxidations of various α-substituted cyclohexanones using either whole-cells of Acinetobacter TD63 or a purified cyclohexanone monooxygenase from Ps. putida NCIMB 10007 (MO2). A refinement of the previously established active site model is proposed.

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Article information

DOI
https://doi.org/10.1039/P19960001867
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1996, 1867-1872

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Comparison of microbiologically and enzymatically mediated Baeyer–Villiger oxidations: synthesis of optically active caprolactones

V. Alphand, R. Furstoss, S. Pedragosa-Moreau, S. M. Roberts and A. J. Willetts, J. Chem. Soc., Perkin Trans. 1, 1996, 1867 DOI: 10.1039/P19960001867

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