Asymmetric synthesis of (1R,1′R)- and (1S,1′S)-bis(1-arylethyl)amines by way of a diastereoselective addition to chiral imines and oxaxolidines with organometallic reagents

Kimio Higashiyama; Hiroaki Inoue; Takayasu Yamauchi; Hiroshi Takahashi

doi:10.1039/P19950000111

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Asymmetric synthesis of (1R,1′R)- and (1S,1′S)-bis(1-arylethyl)amines by way of a diastereoselective addition to chiral imines and oxaxolidines with organometallic reagents

Kimio Higashiyama, Hiroaki Inoue, Takayasu Yamauchi and Hiroshi Takahashi

Abstract

The asymmetric synthesis of the bis(α-methylbenzyl)amines, (1R,1′R)- and (1S,1′S)-bis(1-arylethyl)-amines 6, utilizing a diastereoselective reaction of chiral imines and oxazolidines derived from (R)-phenylglycinol with Organometallic reagents, is described.

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DOI: https://doi.org/10.1039/P19950000111
Article type: Paper

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J. Chem. Soc., Perkin Trans. 1, 1995, 111-115

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Asymmetric synthesis of (1R,1′R)- and (1S,1′S)-bis(1-arylethyl)amines by way of a diastereoselective addition to chiral imines and oxaxolidines with organometallic reagents

K. Higashiyama, H. Inoue, T. Yamauchi and H. Takahashi, J. Chem. Soc., Perkin Trans. 1, 1995, 111 DOI: 10.1039/P19950000111

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Journal of the Chemical Society, Perkin Transactions 1

Asymmetric synthesis of (1R,1′R)- and (1S,1′S)-bis(1-arylethyl)amines by way of a diastereoselective addition to chiral imines and oxaxolidines with organometallic reagents

Abstract

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Asymmetric synthesis of (1R,1′R)- and (1S,1′S)-bis(1-arylethyl)amines by way of a diastereoselective addition to chiral imines and oxaxolidines with organometallic reagents

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