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Issue 3, 1992
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A convenient one-pot synthesis of α-fluoro-α,β-unsaturated nitriles from diethyl cyanofluoromethanephosphonate

Abstract

The carbanion of diethyl 1-cyano-1-fluoromethanephosphonate 3, generated in situ from diethyl cyanomethanephosphonate 2 and N-fluorobis(trifluoromethanesulfonyl)imide 1, undergoes the Wittig–Horner reaction with aldehydes and ketones to yield α-fluoro-α,β-unsaturated nitriles 5.

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Article type: Paper
DOI: 10.1039/P19920000313
J. Chem. Soc., Perkin Trans. 1, 1992, 313-315

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    A convenient one-pot synthesis of α-fluoro-α,β-unsaturated nitriles from diethyl cyanofluoromethanephosphonate

    Z. Xu and D. D. DesMarteau, J. Chem. Soc., Perkin Trans. 1, 1992, 313
    DOI: 10.1039/P19920000313

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