SCHEDULED MAINTENANCE
The 9,9,9-trifluoro analogue of the Wieland–Miescher ketone 15, intended to serve as a precursor of 19,19,9-trifluoro steroids, has been prepared from 2-trifluoromethyl-1,4-benzoquinone 1via a Diels–Alder reaction as the key step.
J. Blazejewski, F. Le Guyader and C. Wakselman, J. Chem. Soc., Perkin Trans. 1, 1991, 1121 DOI: 10.1039/P19910001121
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