The enzymic hydrolysis of 1-methoxyindol-3-ylmethyl glucosinolate (1b) proceeds via the corresponding isothiocyanate (2b), thus providing evidence for a previously unsubstantiated breakdown pathway and establishing a link with 1-methoxycyclobrassinin (4b) and related indole phytoalexins.
A. B. Hanley, K. R. Parsley, J. A. Lewis and G. R. Fenwick, J. Chem. Soc., Perkin Trans. 1, 1990, 2273 DOI: 10.1039/P19900002273
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