SCHEDULED MAINTENANCE
Diazomethane and its alkyl and aryl derivatives react as ylides with tetrasulphur tetranitride in boiling dichloromethane to give the red crystalline 1,3λ4δ2,5,2,4-trithiadiazines (2), (5), and (7). The five contiguous heteroatoms in this new ring system form a planar U-shaped S3N2 unit, very similar to that in S4N2(3) and the dihydrotrithiadiazepine (4).
R. M. Bannister and C. W. Rees, J. Chem. Soc., Perkin Trans. 1, 1989, 2503 DOI: 10.1039/P19890002503
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...