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Issue 3, 1989

Perkin communications. X-Ray structural study of a 1 : 1 complex of 4-methoxy-1-methylpyridone and (R,R)-(–)-1,6-bis(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol the irradiation of which gives optically pure β-lactam

Abstract

A 1 : 1 complex of 4-methoxy-1-methylpyridone and (R,R)-(–)-1,6-bis(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol, on irradiation, gives a pure β-lactam. The mechanism for this photoconversion has been studied by means of an X-ray crystallographic analysis of the complex.

Article information


J. Chem. Soc., Perkin Trans. 1, 1989, 663-664
Article type
Paper

Perkin communications. X-Ray structural study of a 1 : 1 complex of 4-methoxy-1-methylpyridone and (R,R)-(–)-1,6-bis(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol the irradiation of which gives optically pure β-lactam

T. Fujiwara, N. Tanaka, K. Tanaka and F. Toda, J. Chem. Soc., Perkin Trans. 1, 1989, 663 DOI: 10.1039/P19890000663

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