Issue 0, 1986

β-Diketone interactions. Part 1. Pentane-2,4-dione–diethylamine adduct. X-Ray structure reveals novel hydrogen-bonded dimer

Abstract

When mixed, pentane-2,4-dione (PD) and diethylamine (DEA) produce unstable crystals of a 1 : 1 adduct which slowly condense with time to form 4-diethylaminopent-3-en-2-one. An X-ray crystal structure of the adduct shows it to be a dimer with alternate PD and DEA molecules held together by N–H ⋯O hydrogen bonds one of which is a three-centre hydrogen bond.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1986, 471-473

β-Diketone interactions. Part 1. Pentane-2,4-dione–diethylamine adduct. X-Ray structure reveals novel hydrogen-bonded dimer

J. Emsley, N. J. Freeman, R. J. Parker, H. M. Dawes and M. B. Hursthouse, J. Chem. Soc., Perkin Trans. 1, 1986, 471 DOI: 10.1039/P19860000471

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