Issue 0, 1985

Phenylthio migrations in rearrangements of 2,2-bisphenylthioethanols

Abstract

Thionyl chloride causes rearrangement of the title compounds to give 2,3-bisphenylthiopropenes (12) by a [1,2] phenylthio shift. The products undergo [1,3] phenylthio shifts on exposure to light. Some applications to synthesis are described.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1985, 1055-1066

Phenylthio migrations in rearrangements of 2,2-bisphenylthioethanols

P. Blatcher and S. Warren, J. Chem. Soc., Perkin Trans. 1, 1985, 1055 DOI: 10.1039/P19850001055

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