Phosphoenolpyruvate (PEP) has been synthesized from pyruvic acid and dimethyl trimethylsilyl phosphite in high yield by a new route which involves, successively, trimethylsilylation, bromination, and a Perkow reaction. A PEP analogue of 1-(dihydroxyphosphinyl)vinyl phosphate (1) has also been prepared.
M. Sekine, T. Futatsugi, K. Yamada and T. Hata, J. Chem. Soc., Perkin Trans. 1, 1982, 2509 DOI: 10.1039/P19820002509
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