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Issue 12, 1978
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Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 9. New reagents for amination of the ethylenic linkage

Abstract

Treatment of disulphides, especially diphenyl disulphide, with chloramine-T affords a series of reagents which react with olefins to give adducts. These reactions are electrophilic in nature, with PhS+ initiating the reaction and a complex nitrogen anion terminating the process. Similar, but less extensive, experimentation has been carried out with diselenides, especially diphenyl diselenide. These new reagents provide a novel procedure for the amination of the ethylenic linkage.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1978, 1682-1692
Article type
Paper

Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 9. New reagents for amination of the ethylenic linkage

D. H. R. Barton, M. R. Britten-Kelly and D. Ferreira, J. Chem. Soc., Perkin Trans. 1, 1978, 1682
DOI: 10.1039/P19780001682

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