Issue 4, 1977

The halogen–dimethyl sulphoxide system as an oxidizing reagent; a convenient method for preparation of diaryl di- and tri-ketones

Abstract

Some active methylene compounds are oxidized readily by dimethyl sulphoxide to afford the corresponding ketones in the presence of a catalytic amount of iodine and a strong acid. It is suggested that the reaction proceeds via an oxidation–reduction cycle.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1977, 372-374

The halogen–dimethyl sulphoxide system as an oxidizing reagent; a convenient method for preparation of diaryl di- and tri-ketones

N. Furukawa, T. Akasaka, T. Aida and S. Oae, J. Chem. Soc., Perkin Trans. 1, 1977, 372 DOI: 10.1039/P19770000372

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