SCHEDULED MAINTENANCE
Bromofluorination of phenyl-substituted olefins, e.g. 1,1-diphenylethylenes, β-alkylstyrenes, and stilbene, with N-bromosuccinimide–hydrogen fluoride–pyridine in ether proceeds with Markovnikov-type regioselectivity. The reaction is sterospecific (anti) for trans- and nonstereospecific for cis-olefins.
M. Zupan and A. Pollak, J. Chem. Soc., Perkin Trans. 1, 1976, 971 DOI: 10.1039/P19760000971
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