Issue 0, 1973

A photochemical reaction of 2-acetyl-3-alkylamino-1,4-benzoquinones: formation of benzoxazoles

Abstract

A number of 2-acetyl-3-alkylamino-6-anilino-1,4-benzoquinones have been prepared by the reaction of 2-acetyl-3,6-dianilino-1,4-benzoquinone with alkylamines in chloroform solution. Irradiation of 3-methylamino-, 3-n-propylamino-, and 3-phenethylamino-2-acetyl-6-anilino-1,4-benzoquinones in solution gave benzoxazoles and 2-acetyl-3-amino-6-anilino-1,4-benzoquinone.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1973, 493-496

A photochemical reaction of 2-acetyl-3-alkylamino-1,4-benzoquinones: formation of benzoxazoles

R. G. F. Giles, P. R. K. Mitchell, G. H. P. Roos and I. Baxter, J. Chem. Soc., Perkin Trans. 1, 1973, 493 DOI: 10.1039/P19730000493

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